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471.
Seyed Hanif Mahboobi Ali Meghdari Nader Jalili Farshid Amiri 《Central European Journal of Physics》2011,9(2):454-465
Molecular dynamics simulations are carried out to investigate the manipulation of metallic clusters on stepped surfaces. Five
surface forms are considered in the simulations. The system parts are made of pure transition metals and Sutton-Chen many-body
potential is used as interatomic potential. The conditions which are subjected to change in the tests include: materials used
for particles and substrate, and surface step conditions. In addition to qualitative observations, two criteria which represent
the particle deformation and substrate abrasion are utilized as evaluation tools and are computed for each case. Simulation
results show the effect of the aforementioned working conditions on the particle behavior as well as changes in the pushing
forces. Obtaining this sort of knowledge is highly beneficial for further experiments in order to be able to plan the conditions
and routines which guarantee better success in the manipulation process. 相似文献
472.
Mansooreh MOVAHEDI Nader ZABARJAD SHIRAZ Ali EZABADI Marjaneh SAMADIZADEH Mohamad Reza TALEI BAVIL OLYAI 《Turkish Journal of Chemistry》2021,45(5):1609
The mechanism as well the stereochemistry of cascade cycloisomerization of 15–membered triazatriacetylenic macrocycle was investigated theoretically by using M062X/6–31+G(d,p) and M062X/LANL2DZ calculations. The results showed that the mechanism and outcome of the reaction depended on the absence and presence of a transition metal catalyst. So that, in thermal-induced condition, the reaction had to experience several suprafacial concerted reactions including Ene-reaction (DG#=35.38 kcal/mol), Diels–Alder cycloaddition (DG# = 17.16 kcal/mol), and sigmatropic H-shift rearrangement (DG# = 56.21 kcal/mol) to produce diastereoselective fused cis–tetracyclic aromatic bearing a pyrrole moiety by following kinetic considerations. Also, the [2+2+2] cycloaddition mechanism was neglected in thermal–induced conditions because of high activation free Gibbs energy (DG# = 63.90 kcal/mol). In the presence of palladium catalyst, Pd(0) formed an adduct by coordinating to C = C bonds and decreased the DG# of the process to 29.58 kcal/mol, and consequently provided a facilitated media for the reaction to follow the [2+2+2] to produce more stable fused tetracyclic benzenoid aromatic by passing through the lower energy barrier. 相似文献
473.
474.
A series of rhodamine B (RhB) encapsulated zeolitic imidazolate framework-8 (RhB@ZIF-8) composite nanomaterials with different concentrations of guest loadings have been synthesized and characterized in order to investigate their applicability to solid-state white-light-emitting diodes (WLEDs). The nanoconfinement of the rhodamine B dye (guest) in the sodalite cages of ZIF-8 (host) is supported by fluorescence spectroscopic and photodynamic lifetime data. The quantum yield (QY) of the luminescent RhB@ZIF-8 material approaches unity when the guest loading is controlled at a low level: 1 RhB guest per ~7250 cages. We show that the hybrid (luminescent guest) LG@MOF material, obtained by mechanically mixing a suitably high-QY RhB@ZIF-8 red emitter with a green-emitting fluorescein@ZIF-8 “phosphor” with a comparably high QY, could yield a stable, intensity tunable, near-white light emission under specific test conditions described. Our results demonstrate a novel LG@MOF composite system exhibiting a good combination of photophysical properties and photostability, for potential applications in WLEDs, photoswitches, bioimaging and fluorescent sensors. 相似文献
475.
We prove the instability of the Couette flow if the disturbances is less smooth than the Gevrey space of class 2. This shows that this is the critical regularity for this problem since it was proved in [5] that stability and inviscid damping hold for disturbances which are smoother than the Gevrey space of class 2. A big novelty is that this critical space is due to an instability mechanism which is completely nonlinear and is due to some energy cascade. © 2023 The Authors. Communications on Pure and Applied Mathematics published by Wiley Periodicals LLC. 相似文献